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In the sequence of the following reactio...

In the sequence of the following reactions
`CH_3OH overset(HI)to CH_3I overset(KCN)`
`CH_3CN overset("reduction")to X overset(HNO_2)to Y`
X and Y are respectively

A

`CH_3CH_2NH_2 and CH_3CH_2OH`

B

`CH_3CH_2NH_2 and CH_3COOH`

C

`CH_3CH_2OH and CH_3CHO`

D

`CH_3OCH_3and CH_3CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given sequence of reactions, we will go through each step carefully. ### Step 1: Reaction of Methanol with HI The first reaction is: \[ \text{CH}_3\text{OH} \overset{\text{HI}}{\rightarrow} \text{CH}_3\text{I} \] In this reaction, methanol (CH₃OH) reacts with hydroiodic acid (HI) to form methyl iodide (CH₃I). This is a substitution reaction where the hydroxyl group (-OH) of methanol is replaced by an iodide ion (I⁻) from HI. ### Step 2: Reaction of Methyl Iodide with KCN Next, we have: \[ \text{CH}_3\text{I} \overset{\text{KCN}}{\rightarrow} \text{CH}_3\text{CN} \] In this step, methyl iodide (CH₃I) reacts with potassium cyanide (KCN). This is a nucleophilic substitution reaction where the iodide ion is replaced by a cyanide ion (CN⁻), resulting in the formation of acetonitrile (CH₃CN). ### Step 3: Reduction of Acetonitrile Now we proceed to the reduction: \[ \text{CH}_3\text{CN} \overset{\text{reduction}}{\rightarrow} X \] During the reduction of acetonitrile (CH₃CN), it is converted to ethylamine (C₂H₅NH₂). This can be achieved using reducing agents like lithium aluminum hydride (LiAlH₄) or other suitable reducing agents. ### Step 4: Reaction of Ethylamine with HNO₂ Next, we have: \[ X \overset{\text{HNO}_2}{\rightarrow} Y \] Here, ethylamine (C₂H₅NH₂) reacts with nitrous acid (HNO₂). In this reaction, ethylamine is converted into an unstable diazonium salt (C₂H₅N₂⁺Cl⁻). This diazonium salt decomposes to form ethanol (C₂H₅OH) and nitrogen gas (N₂). ### Conclusion Thus, the final compounds X and Y are: - **X**: Ethylamine (C₂H₅NH₂) - **Y**: Ethanol (C₂H₅OH) ### Summary of the Solution - **X** is Ethylamine (C₂H₅NH₂). - **Y** is Ethanol (C₂H₅OH). ---

To solve the given sequence of reactions, we will go through each step carefully. ### Step 1: Reaction of Methanol with HI The first reaction is: \[ \text{CH}_3\text{OH} \overset{\text{HI}}{\rightarrow} \text{CH}_3\text{I} \] In this reaction, methanol (CH₃OH) reacts with hydroiodic acid (HI) to form methyl iodide (CH₃I). This is a substitution reaction where the hydroxyl group (-OH) of methanol is replaced by an iodide ion (I⁻) from HI. ...
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ERRORLESS-ALCOHOLS, PHENOLS AND ETHERS-Assertion & Reason
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  9. Assertion : The major product formed by heating C(6)H(5)CH(2)OCH(3) wi...

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  10. Assertion: The pK(a) of acetic acid is lower than that of phenol. R...

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  11. Assertion : Alcoholic fermentation involves conversion of sugar into...

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  12. Assertion : The water solubility of the alcohols follow the order t-...

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  13. Acid catalysed dehydration of t-butanol is faster than that of n-butan...

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  14. Assertion : Phenols cannot be converted into esters by direct reacti...

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  15. Assertion: Alcohols are easily protonated thena phenols. Reason: Alc...

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  16. Assertion : Phenol is a weak acid than ethanol. Reason : Groups wit...

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  17. Assertion : (CH(3))(3)C-Br and CH(3)CH(2)O"N"a react to form (CH(3))(3...

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  18. Assertion : Rate of hydrolysis of methyl chloride to methanol is highe...

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  19. Assertion. t-Butyl Methyl ether is not prepared by the reaction of t-b...

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  20. Assertion: The ease of dehydration of the following alcohols is R...

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  21. Assertion: Alcohols have higher boiling points than ethers of comparab...

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