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Following compound are given 1. CH3CH2...

Following compound are given
1. `CH_3CH_2OH` 2. `CH_3COCH_3`
3. `CH_3- underset(CH_3)underset(|)(CH)OH` 4. `CH_3OH`
Which of the above compound(s), on being warmed with iodine solution and NaOH , will give iodoform

A

1, 3 and 4

B

Only 2

C

1, 2 and 3

D

1 and 2

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds will give iodoform when warmed with iodine solution and NaOH, we need to identify which of these compounds meet the criteria for the iodoform test. The iodoform test is positive for methyl ketones and for certain alcohols that can be oxidized to methyl ketones. ### Step-by-Step Solution: 1. **Identify the Compounds:** - Compound 1: `CH₃CH₂OH` (Ethanol) - Compound 2: `CH₃COCH₃` (Acetone) - Compound 3: `CH₃C(CH₃)(OH)` (2-Propanol) - Compound 4: `CH₃OH` (Methanol) 2. **Check Each Compound for Iodoform Test:** - **Compound 1: Ethanol (`CH₃CH₂OH`)** - Ethanol is a primary alcohol and does not have the methyl ketone structure. It will not give a positive iodoform test. - **Compound 2: Acetone (`CH₃COCH₃`)** - Acetone is a methyl ketone (it has the structure CH₃C(=O)CH₃). It will give a positive iodoform test. - **Compound 3: 2-Propanol (`CH₃C(CH₃)(OH)`)** - 2-Propanol can be oxidized to acetone (a methyl ketone). Therefore, it will also give a positive iodoform test. - **Compound 4: Methanol (`CH₃OH`)** - Methanol is a primary alcohol and does not have the required structure for the iodoform test. It will not give a positive result. 3. **Conclusion:** - The compounds that will give iodoform when warmed with iodine solution and NaOH are: - **Compound 2: Acetone (`CH₃COCH₃`)** - **Compound 3: 2-Propanol (`CH₃C(CH₃)(OH)`)** ### Final Answer: The compounds that will give iodoform are **2 (Acetone) and 3 (2-Propanol)**. ---

To determine which of the given compounds will give iodoform when warmed with iodine solution and NaOH, we need to identify which of these compounds meet the criteria for the iodoform test. The iodoform test is positive for methyl ketones and for certain alcohols that can be oxidized to methyl ketones. ### Step-by-Step Solution: 1. **Identify the Compounds:** - Compound 1: `CH₃CH₂OH` (Ethanol) - Compound 2: `CH₃COCH₃` (Acetone) - Compound 3: `CH₃C(CH₃)(OH)` (2-Propanol) ...
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ERRORLESS-ALCOHOLS, PHENOLS AND ETHERS-NCERT BASED QUESTIONS (Properties of Alcohols, Phenols and Ethers)
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  2. The hydroxyl compound that gives a precipitate immediately when treate...

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  3. Following compound are given 1. CH3CH2OH 2. CH3COCH3 3. CH3- unde...

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  8. C6H5OH underset(H2SO4) overset(conc.HNO3)to X. X is

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  10. When phenol is heated with phthalic anhydride in concentrated sulphuri...

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  11. Which statement is incorrect

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  12. When phenol reacts with ammonia is presence of ZnCl(2) at 300^(@)C, it...

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  13. Which of the following statements about phenol is correct?

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  14. Phenol is heated with C Cl(4) and alkaline KOH when salicylic acid is ...

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  15. Liebermann's test is answered by

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  16. The reaction of conc. HNO(3) and phenol forms

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  17. Phenol is

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  18. The following reaction is known as

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  19. Benzoylation of phenol in alkaline medium is known as :

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  20. What amount of bromine will be required to convert 4 g of phenol into ...

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