Home
Class 12
CHEMISTRY
Which of the following statements is cor...

Which of the following statements is correct

A

Phenol is less acidic than ethyl alcohol

B

Phenol is more acidic than ethyl alcohol

C

Phenol is more acidic than carboxylic acid

D

Phenol is more acidic than carbonic acid

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is correct regarding the acidity of phenols, alcohols, and carboxylic acids, we can analyze the acidity of the compounds mentioned: ### Step-by-Step Solution: 1. **Understanding Acidity**: - Acidity refers to the ability of a compound to donate a proton (H⁺). The more easily a compound can lose a proton, the stronger its acidity. 2. **Analyzing Phenol**: - Phenol (C₆H₅OH) can lose a proton to form the phenoxide ion (C₆H₅O⁻). The phenoxide ion is resonance-stabilized, meaning the negative charge can be delocalized over the aromatic ring, which increases its stability. 3. **Analyzing Ethyl Alcohol**: - Ethyl alcohol (C₂H₅OH) can lose a proton to form the ethoxide ion (C₂H₅O⁻). The ethoxide ion is not as resonance-stabilized as the phenoxide ion; it is primarily stabilized by inductive effects from the alkyl group, which is less effective than resonance stabilization. 4. **Comparing Acidity**: - Since the phenoxide ion is more stable than the ethoxide ion due to resonance, phenol is more acidic than ethyl alcohol. Therefore, any statement claiming otherwise is false. 5. **Analyzing Carboxylic Acids**: - Carboxylic acids (RCOOH) are generally more acidic than both phenols and alcohols. When a carboxylic acid loses a proton, it forms a carboxylate ion (RCOO⁻), which is also resonance-stabilized, making it more stable than both phenoxide and ethoxide ions. 6. **Conclusion**: - Based on the analysis, we can conclude that: - Phenol is more acidic than ethyl alcohol (True). - Phenol is less acidic than carboxylic acids (True). - Phenol is less acidic than carbonic acid (True). ### Final Answer: The correct statement is: **Phenol is more acidic than ethyl alcohol.**

To determine which statement is correct regarding the acidity of phenols, alcohols, and carboxylic acids, we can analyze the acidity of the compounds mentioned: ### Step-by-Step Solution: 1. **Understanding Acidity**: - Acidity refers to the ability of a compound to donate a proton (H⁺). The more easily a compound can lose a proton, the stronger its acidity. 2. **Analyzing Phenol**: ...
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS, PHENOLS AND ETHERS

    ERRORLESS|Exercise NCERT BASED QUESTIONS (Uses of Alcohols, Phenols and Ethers)|14 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    ERRORLESS|Exercise NCERT BASED QUESTIONS (Methanol and Ethanol)|28 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    ERRORLESS|Exercise Assertion & Reason|20 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise ASSERTION AND REASON|10 Videos