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What is formed when glycerol reacts with...

What is formed when glycerol reacts with `HIO_(4)` ?

A

B

C

D

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The correct Answer is:
B

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A reaction characteristic of vicinal diols is their oxidative cleavage on treatment with periodic acid (HIO_(4)) . The carbon-carbon bond of the vicinal diol uinit is broken and two carbonyl groups result. Periodic acid is reduced to iodic acid (HIO_(3)) Cyclic diols react to give dicarbonyl compounds. The reactions are faster when the hydroxyl gorups are cid than when they are trans but both stereoisomers are oxidised by periodic acid. Periodic acid cleavage of vicinal diols is often used for analytic purposes as an aid in structure determination. By identifying the carbonyl compounds produced, The constitution of the diol may be deduced. Which of the following products is/are obtained when glycerol is treated with HIO_(4) ?

Which of the following is NOT formed when HBr reacts with H_(2)SO_(4) ?

(1) What product would be formed when D-Glucose is treated with HIO_(4) ? (2) D-Threose Why epimers formed are in unequal amounts?

Acrolein is formed when glycerol is heated with

Acrolein is formed when glycerol is heated with :

ERRORLESS-ALCOHOLS, PHENOLS AND ETHERS-NCERT BASED QUESTIONS (Dihydric, Trihydric and Unsaturated Alcohols)
  1. Ethylene glycol reacts with excess of PCl(5) to give :

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  2. Which of the following compounds contain at least one secondary alcoho...

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  3. Which of the following is industrially prepared by passing ethylene in...

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  4. The reaction of ethylene glycol with PI(3) gives :

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  5. CH(2)OH.CH(2)OH on heating with periodic acid gives

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  6. Identify the product of the following reaction:

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  7. Glycerine has

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  8. Benzene on treatment with a mixture of conc.HNO3 and conc. H2SO4 at 10...

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  9. Fats on alkaline hydrolysis, give

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  10. What is formed when glycerol reacts with HIO(4) ?

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  11. When glycerol is heated with KHSO4 it gives

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  12. With oxalic acid, glycerol at 260^(@) C gives

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  13. Glycerol on treatment with oxalic acid at 110^(@)C forms

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  14. Dehydration of glycerol produces

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  15. Glycerol on reaction with NaHCO(3) gives

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  16. Glycerol boils at 290^(@) C slight decomposition Impure glycerine can ...

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  17. On passing vapours of an organic liquid over finely divided Cu at 573K...

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  18. CH(3)-CH=CH-CH(OH)-CH(3)underset("reagent")overset("Jone's")to X, Prod...

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  19. C(6)H(5)-CH=CHCHO overset((X))rarr C(6)H(5)CH=CH(2)OH In the above s...

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  20. The compound which reacts with excess bromine to produce 2, 4, 6-tribr...

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