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Glycerol on reaction with NaHCO(3) gives...

Glycerol on reaction with `NaHCO_(3)` gives

A

Acrolein

B

Acetic Acid

C

Formic acid

D

Propanol

Text Solution

Verified by Experts

The correct Answer is:
A
When glycerol is heated to 2800C, in presence of sodium bicarbonate, it decomposes into acrolein : `(CH_2OH)_2CHOHto underset("Acrolein")(CH_2=CHCHO+2H_2O)`
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Which of the following statement is correct ? i. Glycerol reaction with oxalic acid at 110^(@)C (383K) and followed by heating and hydrolysis gives formic acid and glycerol. ii. Glycerol on reaction with oxalic at 230^(@)C (503K) and followed by heating gives allyl alcohol. iii. Glycerol on oxidation with dil. HNO_(3) gives a mixture of glyceric and tratonic acid. iv. Glycerol on oxidation with conc. HNO_(3) gives glyceric acid.

Which of the following compounds produce CO_(2) on reaction with NaHCO_(3) ?

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ERRORLESS-ALCOHOLS, PHENOLS AND ETHERS-NCERT BASED QUESTIONS (Dihydric, Trihydric and Unsaturated Alcohols)
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