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CH(3) - CH(2) - CH(2) - CH(3) overset(Al...

`CH_(3) - CH_(2) - CH_(2) - CH_(3) overset(AlCl_3) underset(HBr) rarr ` Product. Product in above reaction is

A

`CH_(3) - underset(Br) underset(|)CH-CH_(2) - CH_(3)`

B

`CH_(3) - underset(CH_3)underset(|)CH - CH_(3)`

C

`underset(Br)underset(|)(CH_2)-CH_(2) - underset(CH_3)underset(|)CH_(2)`

D

All of these

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The correct Answer is:
To solve the given reaction of butane (CH₃-CH₂-CH₂-CH₃) with AlCl₃ and HBr, we need to analyze the reaction step by step. ### Step 1: Identify the Reactants The reactant is butane, which has the molecular formula C₄H₁₀. The structure can be represented as: \[ \text{CH}_3-\text{CH}_2-\text{CH}_2-\text{CH}_3 \] ### Step 2: Understand the Role of AlCl₃ AlCl₃ is a Lewis acid that can facilitate the formation of a carbocation by interacting with the alkane. In this case, it helps in the activation of HBr to generate a more reactive species. ### Step 3: Addition of HBr When HBr is added to butane in the presence of AlCl₃, it can lead to the formation of a carbocation. The hydrogen from HBr can add to one of the carbon atoms, and the bromine can attach to the adjacent carbon. ### Step 4: Carbocation Formation The addition of HBr can lead to the formation of a secondary carbocation (more stable than a primary carbocation) if the hydrogen adds to the terminal carbon. The possible carbocations formed can be: 1. CH₃-CH₂-CH₂-CH₂⁺ (primary) 2. CH₃-CH₂-CH⁺-CH₃ (secondary) ### Step 5: Rearrangement and Product Formation Due to the stability of the secondary carbocation, it is more favorable for the reaction to proceed through this pathway. The bromine ion (Br⁻) will then attack the carbocation, leading to the formation of 2-bromobutane. ### Step 6: Final Product The final product of the reaction is 2-bromobutane, which can be represented as: \[ \text{CH}_3-\text{CH}(\text{Br})-\text{CH}_2-\text{CH}_3 \] ### Summary of the Reaction The reaction can be summarized as: \[ \text{CH}_3-\text{CH}_2-\text{CH}_2-\text{CH}_3 \overset{\text{AlCl}_3}{\underset{\text{HBr}}{\rightarrow}} \text{CH}_3-\text{CH}(\text{Br})-\text{CH}_2-\text{CH}_3 \] ### Final Answer The product of the reaction is 2-bromobutane. ---

To solve the given reaction of butane (CH₃-CH₂-CH₂-CH₃) with AlCl₃ and HBr, we need to analyze the reaction step by step. ### Step 1: Identify the Reactants The reactant is butane, which has the molecular formula C₄H₁₀. The structure can be represented as: \[ \text{CH}_3-\text{CH}_2-\text{CH}_2-\text{CH}_3 \] ### Step 2: Understand the Role of AlCl₃ AlCl₃ is a Lewis acid that can facilitate the formation of a carbocation by interacting with the alkane. In this case, it helps in the activation of HBr to generate a more reactive species. ...
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ERRORLESS-HYDROCARBONS-ASSERTION & REASON
  1. CH(3) - CH(2) - CH(2) - CH(3) overset(AlCl3) underset(HBr) rarr Produ...

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  2. Assertion : Cyclopentadienyl anion is much more stable than allyl anio...

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  3. Assertion : Tropylium cation is aromatic in nature Reason : The only...

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  4. Assertion:Cyclobutane is less stable than cyclopentane. Reason : Pre...

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  5. Assertion : Pyrrole is an aromatic heterocyclic compound Reason : ...

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  6. Assertion : CH(4) does not react Cl(2) in dark. Reason: Chlorinat...

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  7. Assertion : Alkyl benzene is not prepared by Friedel- Crafts alkylatio...

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  8. Assertion : 2-Bromobutane on reaction with sodium ethoxide in ethanol ...

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  9. Assertion: Styrence on reaction with HBr gives 1-bromo-1-phenylethane ...

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  10. Assertion :Iodination of alkanes is reversible Reason:Iodination is ...

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  11. Assertion:Freezing point of neopentane is more than n-pentane. Reaso...

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  12. Assertion : The presence of Ag^(+) enhance the solubility of alkenes i...

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  13. Assertion : Propene reacts with HBr in presence of benzoyl peroxide to...

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  14. A) Addition of HBr on 2-butene gives two isomeric products. R) Addit...

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  15. Assertion:Aryl halides are less reactive towards substitution of halog...

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  16. Assertion:Benzene is a solvent for the Friedel Craft's alkylation of b...

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  17. Assertion : [10]Annulene is not aromatic though it contains Huckel num...

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  18. Assertion : Benzene forms benzene sulphonic acid with fuming H2SO4 at ...

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  19. Assertion :Activating groups are electron donors. Reason: Nitroso gr...

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