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The product of following reaction is ...

The product of following reaction is
`CH_(3) underset(CH_3)underset(|)overset(CH_3)overset(|)C-CH = CH_(2) overset( (i) Hg(OAc)_2 , H_(2)O)underset((ii) NaBH_4) rarr`

A

`CH_(3)- overset(CH_3)overset(|)underset(CH_3)underset(|)C-underset(OH)underset(|)CH-CH_(3)`

B

`CH_(3)-overset(CH_3)overset(|)underset(CH_3)underset(|)C-CH_(2)-CH_(2)OH`

C

`CH_(3)-overset(OH)overset(|)underset(CH_3)underset(|)C-overset(CH_3)overset(|)CH-CH_(3)`

D

`HOCH_(2) - overset(CH_3)overset(|)underset(CH_3)underset(|)C-CH_(2) - CH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the reaction given in the question, we will follow these steps: ### Step 1: Identify the Reactants The reactant in the given reaction is 2-methyl-2-pentene (CH₃)₂C=CH-CH₂-CH₃. We also have the reagents: Hg(OAc)₂ and H₂O followed by NaBH₄. ### Step 2: Understand the Reaction Mechanism The reaction involves oxymercuration-demercuration. The first step (oxymercuration) involves the addition of mercuric acetate (Hg(OAc)₂) and water (H₂O) across the double bond. This results in the formation of a mercurinium ion intermediate. ### Step 3: Formation of the Mercurinium Ion When the double bond of 2-methyl-2-pentene reacts with Hg(OAc)₂, a cyclic mercurinium ion is formed. The double bond attacks the mercury, leading to the formation of a three-membered ring structure with a positive charge on the mercury. ### Step 4: Nucleophilic Attack Water (H₂O), which acts as a nucleophile, attacks the more substituted carbon of the mercurinium ion. This results in the formation of an alcohol intermediate. The product at this stage is 2-methyl-2-pentanol. ### Step 5: Demercuration The second step involves the reduction of the mercurial intermediate using sodium borohydride (NaBH₄). This step replaces the mercury group with a hydrogen atom, leading to the final product. ### Step 6: Final Product After the reduction, the final product of the reaction is 2-methyl-2-pentanol (CH₃)₂C(OH)CH₂CH₃. ### Final Answer The product of the reaction is 2-methyl-2-pentanol. ---

To solve the reaction given in the question, we will follow these steps: ### Step 1: Identify the Reactants The reactant in the given reaction is 2-methyl-2-pentene (CH₃)₂C=CH-CH₂-CH₃. We also have the reagents: Hg(OAc)₂ and H₂O followed by NaBH₄. ### Step 2: Understand the Reaction Mechanism The reaction involves oxymercuration-demercuration. The first step (oxymercuration) involves the addition of mercuric acetate (Hg(OAc)₂) and water (H₂O) across the double bond. This results in the formation of a mercurinium ion intermediate. ...
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ERRORLESS-HYDROCARBONS-NCERT BASED QUESTION (ALKENE)
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  2. Presence of peroxides affects the addition of

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  3. The product of following reaction is CH(3) underset(CH3)underset(|)...

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  4. Position of double bond in an organic compound is determined by

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  5. Indicate the organic structure for the product expected when 2-methylp...

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  6. What type of reaction is involved is the reaction CH(2) - CH - CH(3) +...

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  7. The reaction of CH(3)CH=CH(2) with HOCl will yield

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  8. One mole of a symmetrical alkene on ozonolysis gives two moles of an a...

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  9. The major products obtained during ozonolysis of 2,3-dimethyl-1-butene...

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  10. The addition of HBr is the easiest with

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  11. Which of the following alkenes will react fastest with H(2) under cata...

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  12. The reagent X in the reactions (CH3)3C CH=CH2 underset"THF"oversetX ...

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  13. The addition of HBr of 1-butene gives a mixture of products A,B and C ...

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  14. Which of the following will not show geometrical isomerism ?

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  15. Hydroboration oxidation of 4-methyl octene would give

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  16. What is the order of reactivity of these alkenes (CH(3))(2)C=CH(2)(I...

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  17. In the following reaction 2CH(2) = CH(2) + S(2)Cl(2) rarr Product. T...

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  18. When ethene is heated at 400^@ C Under high pressure, the product is a...

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  19. CH2=CH2underset(KOH//H2O)overset(KMnO4)to X. Product 'X' in above reac...

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  20. Identify Z in the series CH2=CH2overset"HBr" to X overset"aq.KOH"to ...

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