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[A] overset("lindlar's")underset("cataly...

`[A] overset("lindlar's")underset("catalyst")larr CH_(3) - C -= C -CH_(3) overset("Na in ")underset(liq. NH_3)rarr [B]`
[A] and [B] are respectively

A

C is trans -2- butene

B

Both trans-2-butene

C

Trans, cis-2-butene

D

Both cis-2-butene

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The correct Answer is:
To solve the question, we need to identify the compounds [A] and [B] based on the given reactions involving Lindlar's catalyst and sodium in liquid ammonia. ### Step-by-Step Solution: 1. **Identify Compound [A]:** - The starting compound is given as CH₃ - C≡C - CH₃, which is 2-butyne (an alkyne). - When 2-butyne undergoes partial hydrogenation in the presence of Lindlar's catalyst, it converts to a cis-alkene. - The product of this reaction is cis-2-butene (cis-CH₃-CH=CH-CH₃). - Therefore, [A] is 2-butyne (CH₃ - C≡C - CH₃). 2. **Identify Compound [B]:** - The second part of the reaction involves the reduction of the same alkyne (2-butyne) using sodium in liquid ammonia. - This reaction leads to the formation of a trans-alkene. - The product of this reaction is trans-2-butene (trans-CH₃-CH=CH-CH₃). - Therefore, [B] is trans-2-butene. ### Final Answer: - [A] is 2-butyne (CH₃ - C≡C - CH₃). - [B] is trans-2-butene (trans-CH₃-CH=CH-CH₃).

To solve the question, we need to identify the compounds [A] and [B] based on the given reactions involving Lindlar's catalyst and sodium in liquid ammonia. ### Step-by-Step Solution: 1. **Identify Compound [A]:** - The starting compound is given as CH₃ - C≡C - CH₃, which is 2-butyne (an alkyne). - When 2-butyne undergoes partial hydrogenation in the presence of Lindlar's catalyst, it converts to a cis-alkene. - The product of this reaction is cis-2-butene (cis-CH₃-CH=CH-CH₃). ...
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ERRORLESS-HYDROCARBONS-NCERT BASED QUESTION (ALKYNE)
  1. Towards electrophilic reagents

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  2. The reagent which is used to distinguish between propene and propyne i...

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  3. [A] overset("lindlar's")underset("catalyst")larr CH(3) - C -= C -CH(3)...

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  4. When propyne reacts with aqueous H(2)SO(4) in the presence of HgSO(4)...

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  5. Ammonical cuprous chloride will give red precipitate with which one of...

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  6. When 2-butyne is treated with H(2)//Pd - BaSO(4), the product formed w...

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  7. Which of the following reactions will yield 2,2-dibromopropane ?

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  8. CaC(2)+H(2)Orarr A overset(H(2)SO(4) // HgSO(4)) rarr B. Identify A an...

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  9. The decreasing order of acidic character among ethane(I), ethene(II), ...

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  10. Ph-CequivC - CH(3) overset(Hg^(2+)//H^(+))(rarr)A

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  11. In order to complete the reaction 1 - "Pentyne" overset(a) rarr 4 - ...

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  12. Arrange the following carbanions in order of their decreasing stabilit...

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  13. Electrophilic addition reaction is easily given by

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  14. What is the major product of the following reaction ? CH(3)C-=C-CH(2)...

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  15. A compound C5H8 which gives white ppt. with ammonical AgNO3.A give (CH...

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  16. Identify X in the following sequence of reactions CH(3) - underset(...

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  17. Which one of the following characteristics apply to both ethene and et...

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  18. A gas decolourises KMnO4 solution but gives no precipitate with ammoni...

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  19. Acetylenic hydrocarbons are acidic because

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  20. Lewisite, a chemical weapon, is prepared by the reaction of acetylene ...

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