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Electrophilic addition reaction is easil...

Electrophilic addition reaction is easily given by

A

Acetylene

B

Ethene

C

Ethane

D

Benzene

Text Solution

Verified by Experts

The correct Answer is:
B

Inspite of the fact that the two `pi`-bonds are present in alkynes, these are less reactive than alkenes towards addition reactions (due to symmetrical cylindrical nature of `pi` - electron cloud.) Further, alkynes do not show geometrical isomerism due to their linear structure.
The `pi` - electrons of alkynes are more tightly attached to the carbon atoms than `pi`-electrons in alkene and hence less easily available for addition reactions with electrophiles. As a result, alkynes are less reactive than alkenes towards electrophilic addition reaction. A majority of addition reactions of alkynes are catalysed by heavy metal ions such as `Hg^(2+)` and `Ba^(2+)` etc.while no such catalysts are needed in case of electrophilic addition reactions to alkenes.
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Electrophilic addition on alkenes

Electrophilic Addition Reaction |Summary

Both electrophilic and nucleophilic additon reaction are given by

Explain the mechanism of electrophilic addition reactions of alkenes.

Electrophilic additions reactions proceed in two steps. The first step involves the additions of an electrophile. Name the type of intermediate formed in the first step of the following addition reaction H_(3)C - HC = CH_(2) + H^(+) rarr ?

Alkenes and carbonyl compounds both contain a pi bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.

What are alkenes ? Why do these show geometrical isomerism? Explain the mechanism of electrophilic addition reactions to alkenes.

Assertion(A):Benzene does not show electrophilic addition reaction: Reason Benzene is a cyclic unsaturated hydrocarbon.

ERRORLESS-HYDROCARBONS-NCERT BASED QUESTION (ALKYNE)
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  2. Arrange the following carbanions in order of their decreasing stabilit...

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  3. Electrophilic addition reaction is easily given by

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  4. What is the major product of the following reaction ? CH(3)C-=C-CH(2)...

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  5. A compound C5H8 which gives white ppt. with ammonical AgNO3.A give (CH...

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  6. Identify X in the following sequence of reactions CH(3) - underset(...

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  7. Which one of the following characteristics apply to both ethene and et...

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  8. A gas decolourises KMnO4 solution but gives no precipitate with ammoni...

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  9. Acetylenic hydrocarbons are acidic because

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  10. Lewisite, a chemical weapon, is prepared by the reaction of acetylene ...

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  11. Acetylene can be prepared from

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  12. A compound is treated with NaNH(2) to give sodium salt. Identify the c...

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  13. KMnO4 will oxidised acetylene to

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  14. Which of the following reagents distinguish ethylene from acetylene?

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  15. If acetylene is passed through an electric arc in the atmosphere of ni...

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  16. Acetylene is prepared industrially by passing electric discharge throu...

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  17. When acetylene is passed into dilute sulphuric acid containing Hg^"2+...

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  18. Acetylene adds on to HCN gives

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  19. What happens when a mixture of acetylene and hydrogen is passed over h...

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  20. Catalyst used in dimerisation of acetylene to prepare chloroprene is

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