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Excess of CH(3)COOH is reacted with CH-=...

Excess of `CH_(3)COOH` is reacted with `CH-=CH` in presence of `Hg^(2+)`, the product is -

A

`overset(CH_3)overset(|)CH(CH_3COO)_2`

B

`{:(CH(CH_3COO)_2),(|),(CH(CH_3COO)_2):}`

C

`overset(CH_3)overset(|)CH_(2)(CH_3COO)`

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
A

Reaction of acetic acid with acetylene is catalysed by `Hg^(2+)` salts.
`underset("Acetylene")(HC=CH) overset(CH_3COOH)underset(Hg(OOC CH_3)_2)rarrCH_(2)=underset("vinyl acetate")(CHOOC CH_3)overset(CH_3COOH)underset(Hg(OOC CH_3)_2)rarrCH_3-underset("ethylidene diacetate")(CH(OO C CH_3)_2)`
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