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In the following reactions,...

In the following reactions,

A

`CH_(3)- overset(CH_3)overset(|)CH-underset(OH)underset(|)CH-CH_(3) overset(H^+//heat)rarr underset("Major product")(A) + underset("Minor Product")B`

B

`A overset(HBr, dark) underset("in absence of peroxide") rarr underset(("Mejor product"))C + underset("(Minor product)")(D)`
The major products (A) and (C) are respectively

C

`CH_(2) = overset(CH_3) and CH_(3) and CH_(3) - overset(CH_3)overset(|)underset(Br) underset(|)C-CH_(2) - CH_(3)`

D

`CH_(3)- overset(CH_3)overset(|)C=CH - CH_(3) and CH_(3) - overset(CH_3)overset(|)(CH)-underset(Br)underset(|)CH-CH_(3)`

Text Solution

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The correct Answer is:
C

`CH_(3)-overset(CH_3)overset(|)(CH)-underset(OH)underset(|)CH-CH_(3) overset(H^+)underset(Delta) rarr`
`CH_(3) - overset(CH_3)overset(|)underset("major")underset("(A)")C=CH-CH_3 + CH_(3) overset(CH_3)overset(|)underset("minor")underset((B))CH-CH = CH_(2)`
`H_(3)C-overset(CH_3)overset(|)underset((A))underset("major")C=Ch-CH_(3) overset(HBr(dark)) rarr`
`CH_(3)-underset((C)"major")underset(Br)underset(|)overset(CH_3)overset(|)C-CH-CH_(3) + CH_(3)-overset(CH_3)overset(|)underset("(D)marjor")underset(H)underset(|)C-underset(Br)underset(|)CH-CH_3`
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