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When 3,3-dimethyl-2-butanol is heated wi...

When `3,3-`dimethyl`-2-`butanol is heated with `H_(2)SO_(4)` the major product obtained is

A

Cis and trans isomers of 2, 3-dimethyl-2-butene

B

3, 3-dimethyl-1-butene

C

2, 3-dimethyl-2-butene

D

2, 3-dimethyl-1-butene

Text Solution

Verified by Experts

The correct Answer is:
C

`underset("3,3-dimethyl - 2-butanol")(CH_(3)-underset(OH)underset(|)CH-overset(CH_3)overset(|)C-CH_3 overset(H_2SO_4)rarr)`
`CH_(3)- overset(+)(CH)-overset(CH_3)overset(|)underset(2^@ "carboniumion")underset(CH_3)underset(|)C-CH_3 + OH^(-) overset("methyl shif")underset("rearrangement")rarr`
`underset("[Most symmetrial Structure]")underset("2,3- dimethyl-2-Butene")(CH_3-overset(CH_3)overset(|)C=overset(CH_3)overset(|)C-CH_(3)) underset(-H^+)larr underset(3^@ "Carbonium ion (Morestable)")(CH_3-overset(CH_3)overset(|)CH-overset(CH_3)overset(|)underset(+)(C)-CH_(3))`
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ERRORLESS-HYDROCARBONS-PAST YEAR QUESTIONS
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  2. In the following reactions,

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  3. When 3,3-dimethyl-2-butanol is heated with H(2)SO(4) the major product...

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  4. Alkynes usually show which type of reaction ?

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  5. Baeyer's reagent is used in the laboratory for-

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  6. Olefins can be hydrogenated by :

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  7. Which of the following compound is produced when CH2=CH-(CH2)2COOH rea...

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  8. A hgydrocarbon X adds on one mole of hydrogen to gives another hydroca...

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  9. CH(3)-underset(CH(3))underset(|)(CH)-CH=CH(2)+HBr to 'A' 'A' (predom...

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  10. The reaction of C(6) H(5) CH=CHCH(3) with HBr produces :

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  11. Reaction of HBr with propene in the presence of peroxide gives :-

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  12. Using anhydrous AlCl(3) as catalyst, which one of the following reacti...

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  13. Identity Z in the sequence of reactions, CH3CH2CH=CH2overset(HBr//H2O2...

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  14. The compound CH(3)-overset(CH(3))overset(|)C=CH-CH(3) on reaction wi...

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  15. Formation of polyethylene from calcium carbide takes place as follows ...

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  16. Which of the compounds with molecular formula C(5)H(10)yields acetone ...

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  17. In the following reaction H(3)C-underset(CH(3))underset(|)overset(CH...

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  18. 2,3-Dimethyl-2-butene can be prepared by heating which of the followin...

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  19. In the reaction sequence CH(2)=CH(2) overset("hydrochlorous")underse...

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  20. Which of the following compounds represents acrylonitrile

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