Home
Class 12
CHEMISTRY
For a cell involving one electron E(cell...

For a cell involving one electron `E_(cell)^(0)=0.59V` and 298K, the equilibrium constant for the cell reaction is:
[Given that `(2.303RT)/(F)=0.059V` at `T=298K`]

A

`1.0 xx 10^(30)`

B

`1.0 xx 10^(2)`

C

`1.0 xx 10^(5)`

D

`1.0 xx 10^(10)`

Text Solution

Verified by Experts

The correct Answer is:
D

Nernst equation `E_("cell")^(Ɵ)= E_("cell")^(Ɵ)= (-0.059)/(n) log Q_(C)`
at equilibrium `E_("cell")= 0, Q_(C)= K_(C)`
`E_("cell")^(Ɵ)= (-0.059)/(n) log K_(C)` Value of `E_("cell")^(Ɵ)= 0.59V`
`0.59 = (0.059)/(1) log K_(C)` value of n=1
`K_(C)`= antilog 10
`K_(C)= 1 xx 10^(10)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    ERRORLESS|Exercise Assertion & Reason|11 Videos
  • ELECTROCHEMISTRY

    ERRORLESS|Exercise NCERT BASED QUESTIONS (Corrosion)|8 Videos
  • COORDINATION COMPOUNDS

    ERRORLESS|Exercise ASSERTION AND REASON|7 Videos
  • GENERAL PRINCIPLES & PROCESSES OF ISOLATION OF ELEMENTS

    ERRORLESS|Exercise ASSERTION & REASON|8 Videos

Similar Questions

Explore conceptually related problems

For a cell involving two electron change , E_(cell)^(@) = 0.3 V at 25^(@) C . The equilibrium constant of the reaction is

The standard emf for the cell reaction, 2Cu^(+)(aq)to2Cu(s)+Cu^(2+)(aq) is 0.36V at 298K . The equilibrium constant of the reaction is

The E_("cell") of the reaction MnO_(4)^(-)+Fe^(+2)+H^(+)rarrMn^(+)+H_(2)O is 0.59 V at 25^(@)C The equilibrium constant for the reaction is

ERRORLESS-ELECTROCHEMISTRY-PAST YEARS QUESTIONS
  1. The standard redox potentials for the reactions, MN^(2+) + 2e^(-)to M...

    Text Solution

    |

  2. For the cell reaction Cu^(2+)(C(1),aq.)+Zn(s)hArrZn^(2+)(C(2),aq)+Cu...

    Text Solution

    |

  3. For the reduction of silver ions with copper metal, the standard cell ...

    Text Solution

    |

  4. The emf of a Daniell cell at 298 K is E(1) Zn|ZnSO(4)(0.01 M)||CuSO(...

    Text Solution

    |

  5. A hydrogen gas electrode is made by dipping platinum wire in a solutio...

    Text Solution

    |

  6. The pressure of H(2) required to make the potential of H(2^(-)) electr...

    Text Solution

    |

  7. The oxidation potential of a hydrogen electrode at pH = 10 and P(H(2))...

    Text Solution

    |

  8. Standard reduction potentails of the half reactions are given below: ...

    Text Solution

    |

  9. Four successive members of the first series of the transition metals a...

    Text Solution

    |

  10. On the basis of the following E^(@) values, the stongest oxidizing age...

    Text Solution

    |

  11. A solution contains Fe^(2+), Fe^(3+) and T^(-) ions. This solution was...

    Text Solution

    |

  12. The emf of a Daniell cell at 298 K is E(1) Zn|ZnSO(4)(0.01 M)||CuSO(...

    Text Solution

    |

  13. If the E(cell)^(@) for a given reaction has a positive value, then whi...

    Text Solution

    |

  14. For the cell reaction: 2Fe^(3+)(aq)+2l^(-)(aq)to2Fe^(2+)(aq)+l(2)(aq...

    Text Solution

    |

  15. For a cell involving one electron E(cell)^(0)=0.59V and 298K, the equi...

    Text Solution

    |

  16. Zine can be coated on iron to produce galvanize3d iron but the reverse...

    Text Solution

    |

  17. On elctrolysis of dil sulphuric acid using Platinum (Pt) electrode the...

    Text Solution

    |

  18. The number of Faradays(F) required to produce 20g of calcuim from molt...

    Text Solution

    |

  19. The molar conductance of NaCl, HCl and CH(3)COONa at infinite dilution...

    Text Solution

    |

  20. The molar conductivity of 0.007 M acetic acid is 20S cm^(2) mol^(-1). ...

    Text Solution

    |