Home
Class 12
CHEMISTRY
Which one of the following does not form...

Which one of the following does not form sodium bisulphite addition product with sodium bisulphite solution

A

`CH_3OH`

B

`C_6H_5COCH_3`

C

`C_6H_5CHO`

D

`CH_3CHO`

Text Solution

Verified by Experts

The correct Answer is:
B

Crystalline solid derivatives are formed when aldehydes or ketones are shaken with saturated aqueous solution of sodium bisulphite, but sodium bisulphite is a bigger nucleophile so, all ketones do not give this test. Only aliphatic methyl ketones form addition product with sodium bisulphite.
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise NCERT BASED QUESTIONS(FORMALDEHYDE)|6 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise NCERT BASED QUESTIONS(ACETALDEHYDE)|14 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise NCERT BASED QUESTIONS(PREPARATION OF ALDEHYDES AND KETONES)|36 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    ERRORLESS|Exercise Assertion & Reason|20 Videos
  • BIOMOLECULES

    ERRORLESS|Exercise ASSERTION & REASON |16 Videos

Similar Questions

Explore conceptually related problems

Which of the following compounds not react with sodium bisulphite

Which of the following does not react with sodium metal ?

Which of the following mineral does not contain sodium ?

Which of following does not react with NaHSO_(3) (sodium bisulphite)?

Which of the following compounds does not react with sodium?

Benzaldehyde forms addition product with sodium bisulphite but acetophenone does not.

Addition Of Sodium Bisulphite

Which of the following statements are correct about the bisulphite addition product of a carbonyl compound ?

ERRORLESS-ALDEHYDES AND KETONES-NCERT BASED QUESTIONS(PROPERTIES OF ALDEHYDES AND KETONES)
  1. C3H6O did not give a silver mirror with Tollen's reagent, but gave an ...

    Text Solution

    |

  2. An aromatic compound X with molecular formula C(9)H(10)O gives followi...

    Text Solution

    |

  3. Which one of the following does not form sodium bisulphite addition pr...

    Text Solution

    |

  4. Which one of the following undergoes reaction with 50% sodium hydroxid...

    Text Solution

    |

  5. OHC-CHOoverset(OH^(-))toHOH(2)C-COOH. The reaction given is

    Text Solution

    |

  6. The correct order of reactivity of PhMgBr with underset((I))(Ph-unde...

    Text Solution

    |

  7. Claisen condensation is not given by

    Text Solution

    |

  8. Ketones reacting with Mg-Hg over water give

    Text Solution

    |

  9. A compound (A) C(5)H(10) Cl(2) on hydrolysis gives C(5)H(10)O which re...

    Text Solution

    |

  10. With which of the following reagents, carbonyl compound shows addition...

    Text Solution

    |

  11. The product of this reaction is

    Text Solution

    |

  12. Aldehydes that do not undergo aldol condensation are (1) propanal (...

    Text Solution

    |

  13. Anils are formed by the condensation of aniline with

    Text Solution

    |

  14. An organic compound 'A' burns with a sooty flame. It is negative towar...

    Text Solution

    |

  15. Which of the follwing compound does not react with concentrated alkali...

    Text Solution

    |

  16. An organic compound 'X' is oxidised by using acidified K(2)Cr(2)O(7). ...

    Text Solution

    |

  17. Which of the following will fail to react with potassium dichromate an...

    Text Solution

    |

  18. Aldehyde and ketones can decolourise

    Text Solution

    |

  19. CH-=CH underset("dil. "H2SO4)overset(HgSO4)to A underset(NaOH)overset(...

    Text Solution

    |

  20. The key step in cannizzaro's reaction is the intermolecular shift of

    Text Solution

    |