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CH-=CH underset("dil. "H2SO4)overset(HgS...

`CH-=CH underset("dil. "H_2SO_4)overset(HgSO_4)to A underset(NaOH)overset("dilute")to B` The compound B is

A

`CH_3-underset(OH)underset(|)(CH)-CH_2-CHO`

B

`CH_3-underset(OH)underset(|)(CH)-CH_2-COONa`

C

`CH_3-underset(OH)underset(|)(CH)-CH_2-overset(O)overset(||)C-CH_3`

D

`CH_3-underset(CH_3)underset(|)overset(OH)overset(|)(CH)-CH_2-overset(O)overset(||)C-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we need to analyze the given reactions and determine what compound B is after the reactions have taken place. ### Step 1: Identify the starting compound The starting compound is an alkyne with the formula CH≡CH (ethyne or acetylene). ### Step 2: Reaction with dilute H₂SO₄ When ethyne (CH≡CH) reacts with dilute sulfuric acid (H₂SO₄) in the presence of mercury(II) sulfate (HgSO₄), it undergoes hydration. This reaction converts the alkyne into a carbonyl compound (an aldehyde or a ketone) through the formation of an enol intermediate that tautomerizes to the carbonyl compound. The product A from this reaction is acetaldehyde (CH₃CHO). **Reaction:** \[ \text{CH} \equiv \text{CH} + \text{H}_2\text{SO}_4 \xrightarrow{\text{HgSO}_4} \text{CH}_3\text{CHO} \] ### Step 3: Reaction with NaOH (dilute) Next, we take compound A (acetaldehyde, CH₃CHO) and react it with dilute sodium hydroxide (NaOH). In this case, the reaction likely involves an aldol condensation if there is enough concentration of the aldehyde. However, since we are using dilute NaOH, it may lead to the formation of a hemiacetal or a simple aldol product. In the case of acetaldehyde, the reaction with dilute NaOH will lead to the formation of a β-hydroxy aldehyde (aldol product) through self-condensation. The product B from this reaction is 3-hydroxybutanal (CH₃CH(OH)CH₂CHO). **Reaction:** \[ 2 \text{CH}_3\text{CHO} \xrightarrow{\text{NaOH (dilute)}} \text{CH}_3\text{CH(OH)CH}_2\text{CHO} \] ### Conclusion The compound B is 3-hydroxybutanal. ---

To solve the problem step by step, we need to analyze the given reactions and determine what compound B is after the reactions have taken place. ### Step 1: Identify the starting compound The starting compound is an alkyne with the formula CH≡CH (ethyne or acetylene). ### Step 2: Reaction with dilute H₂SO₄ When ethyne (CH≡CH) reacts with dilute sulfuric acid (H₂SO₄) in the presence of mercury(II) sulfate (HgSO₄), it undergoes hydration. This reaction converts the alkyne into a carbonyl compound (an aldehyde or a ketone) through the formation of an enol intermediate that tautomerizes to the carbonyl compound. ...
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ERRORLESS-ALDEHYDES AND KETONES-NCERT BASED QUESTIONS(PROPERTIES OF ALDEHYDES AND KETONES)
  1. Which of the following will fail to react with potassium dichromate an...

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  2. Aldehyde and ketones can decolourise

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  3. CH-=CH underset("dil. "H2SO4)overset(HgSO4)to A underset(NaOH)overset(...

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  4. The key step in cannizzaro's reaction is the intermolecular shift of

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  5. In which of the following reactions, the product obtained is chiral ?

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  6. One of the following named reaction is an example of "disproportionati...

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  7. Which of the following reactions will not result in the formation of c...

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  8. Ethylene is converted to X on passing through a mixture of acidified a...

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  9. PCI5 reacts with propanone, to give

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  10. Predict the product

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  11. The compound that neither forms semicarbazone nor oxime is

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  12. The most stabl enol tautomer of MeCOCH(2)CO(2)Et is

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  13. Which of the following will form two isomers with semi carbazide

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  14. Identify the correct statement

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  15. When NH(2)OH reacts with an usymmetrical ketone then numver of product...

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  16. The correct sequence of steps involved in the mechanism of cannizzaro'...

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  17. Which alkene is formed from the following ylide carbonyl pair CH(3)C...

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  18. The major organic product formed from the following reaction

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  19. Consider the following reactions I. H3C Cl3 overset(OH^(Ɵ))to II. ...

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  20. In the following reaction The major product X is

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