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Consider the following reactions I. H3...

Consider the following reactions
I. `H_3C Cl_3 overset(OH^(Ɵ))to`
II. `H_3C CHO overset([Ag(NH_3)_2]^(+)OH^(Ɵ))to`
III. `H_3C CO_2C_2H_5 overset(OH^(Ɵ))to`
Carboxylic acid is the final product only in the reaction (s)

A

I, II

B

II, III

C

II

D

III

Text Solution

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The correct Answer is:
To determine which of the given reactions produces a carboxylic acid as the final product, let's analyze each reaction step by step. ### Step 1: Analyze Reaction I **Reaction I:** `H3C Cl3 + OH^- → ?` In this reaction, we have a trichloromethane (H3C Cl3) reacting with hydroxide ions (OH^-). The hydroxide ion acts as a nucleophile and will replace the chlorine atoms in a nucleophilic substitution reaction. 1. The reaction will proceed through a series of steps where each Cl atom is replaced by OH. 2. However, the final product will not be a carboxylic acid; instead, it will yield an alcohol (H3C OH) after all Cl atoms are replaced. **Conclusion for Reaction I:** No carboxylic acid is formed. ### Step 2: Analyze Reaction II **Reaction II:** `H3C CHO + [Ag(NH3)2]+ OH^- → ?` This reaction involves an aldehyde (H3C CHO) reacting with Tollens' reagent, which is [Ag(NH3)2]+ in the presence of OH^-. 1. The aldehyde is oxidized to a carboxylic acid in the presence of Tollens' reagent. 2. The reaction will convert the aldehyde (H3C CHO) into acetic acid (H3C COOH). **Conclusion for Reaction II:** A carboxylic acid is formed. ### Step 3: Analyze Reaction III **Reaction III:** `H3C CO2C2H5 + OH^- → ?` In this reaction, we have an ester (H3C CO2C2H5) reacting with hydroxide ions (OH^-). 1. The ester undergoes hydrolysis in the presence of a base (OH^-), leading to the formation of a carboxylate ion (H3C COO^-) and an alcohol (C2H5OH). 2. If the reaction is carried out under acidic conditions, the carboxylate ion can be protonated to form a carboxylic acid (H3C COOH). **Conclusion for Reaction III:** A carboxylic acid is formed. ### Final Conclusion: The reactions that yield a carboxylic acid as the final product are: - Reaction II: `H3C CHO + [Ag(NH3)2]+ OH^- → H3C COOH` - Reaction III: `H3C CO2C2H5 + OH^- → H3C COOH (after hydrolysis)` Thus, the reactions that produce a carboxylic acid are **II and III**. ---

To determine which of the given reactions produces a carboxylic acid as the final product, let's analyze each reaction step by step. ### Step 1: Analyze Reaction I **Reaction I:** `H3C Cl3 + OH^- → ?` In this reaction, we have a trichloromethane (H3C Cl3) reacting with hydroxide ions (OH^-). The hydroxide ion acts as a nucleophile and will replace the chlorine atoms in a nucleophilic substitution reaction. 1. The reaction will proceed through a series of steps where each Cl atom is replaced by OH. ...
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