Home
Class 12
CHEMISTRY
The reaction of acetone with PCl5 gives...

The reaction of acetone with `PCl_5` gives

A

`CH_3 COCH_2 Cl`

B

`CH_3COCHCl_2`

C

D

`ClCH_2 COCH_2 Cl`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of acetone with phosphorus pentachloride (PCl₅), we will follow these steps: ### Step 1: Identify the Structure of Acetone Acetone is a simple ketone with the chemical formula \( C_3H_6O \). Its structure can be represented as: \[ \text{CH}_3 - \text{C}(=O) - \text{CH}_3 \] This shows that acetone has a carbonyl group (C=O) flanked by two methyl groups (CH₃). ### Step 2: Understand the Reaction with PCl₅ Phosphorus pentachloride (PCl₅) is a reagent that can react with carbonyl compounds. In this reaction, PCl₅ will react with the carbonyl oxygen of acetone. ### Step 3: Reaction Mechanism When acetone reacts with PCl₅, the carbonyl oxygen atom will be replaced by two chlorine atoms. The mechanism involves the formation of a chlorinated product where the carbonyl group (C=O) is converted into a dichlorinated compound. ### Step 4: Write the Reaction The reaction can be summarized as follows: \[ \text{CH}_3 - \text{C}(=O) - \text{CH}_3 + PCl_5 \rightarrow \text{CH}_3 - \text{C}(Cl)_2 - \text{CH}_3 + POCl_3 \] Here, the product formed is 2,2-dichloropropane (the chlorinated derivative of acetone), and phosphorus oxychloride (POCl₃) is produced as a byproduct. ### Step 5: Conclusion Thus, the reaction of acetone with PCl₅ gives 2,2-dichloropropane and phosphorus oxychloride as the byproduct. ### Final Answer The reaction of acetone with PCl₅ gives 2,2-dichloropropane and POCl₃. ---

To solve the question regarding the reaction of acetone with phosphorus pentachloride (PCl₅), we will follow these steps: ### Step 1: Identify the Structure of Acetone Acetone is a simple ketone with the chemical formula \( C_3H_6O \). Its structure can be represented as: \[ \text{CH}_3 - \text{C}(=O) - \text{CH}_3 \] This shows that acetone has a carbonyl group (C=O) flanked by two methyl groups (CH₃). ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise NCERT BASED QUESTIONS(BENZALDEHYDE)|17 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise NCERT BASED QUESTIONS(ACETOPHENONE AND BENZOPHENONE)|10 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise NCERT BASED QUESTIONS(ACETALDEHYDE)|14 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    ERRORLESS|Exercise Assertion & Reason|20 Videos
  • BIOMOLECULES

    ERRORLESS|Exercise ASSERTION & REASON |16 Videos

Similar Questions

Explore conceptually related problems

Acetic acid on reaction with PCl_(5) gives compound.

Write the chemical reaction of enthanol with PCl_(5) and PCl_(3) separately.

Acetamide when heated with PCl_5 gives

The reaction of chloroform with acetone gives

Knowledge Check

  • The reaction of acetone with PCI_(5) gives

    A
    `CH_(3)COCH_(2)CI`
    B
    `CH_(3)COCHCI_(2)`
    C
    D
    `CICH_(2)COCH_(2)CI`
  • Acetic acid on reaction with PCl_(5) gives compound.

    A
    `CH_(3)COOPCl_(3)`
    B
    `CH_(3)COOCl`
    C
    `CH_(3)COCl`
    D
    `ClCH_(2)COOH`
  • Acetone on reaction with NH_(3) gives

    A
    Dimer of acetone
    B
    `alpha`-Aminoacetone
    C
    Amino acid
    D
    Diacetonamine.