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In the presence of a dilute base C6H5CHO...

In the presence of a dilute base `C_6H_5CHO` and `CH_3CHO` react together to give a product. The product is

A

`C_6H_5CH_3`

B

`C_6H_5CH_2CH_2OH`

C

`C_6H_5CH_2OH`

D

`C_6H_5CH = CHCHO`

Text Solution

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The correct Answer is:
To solve the problem of what product is formed when benzaldehyde (C₆H₅CHO) and acetaldehyde (CH₃CHO) react in the presence of a dilute base, we can follow these steps: ### Step 1: Identify the Reactants The reactants are benzaldehyde (C₆H₅CHO) and acetaldehyde (CH₃CHO). Benzaldehyde is an aromatic aldehyde, while acetaldehyde is an aliphatic aldehyde. **Hint:** Remember that the structure of the aldehydes is crucial for understanding the reaction mechanism. ### Step 2: Understand the Reaction Type The reaction between two aldehydes in the presence of a dilute base typically leads to an aldol condensation reaction. In this reaction, one aldehyde acts as a nucleophile and the other as an electrophile. **Hint:** Aldol condensation involves the formation of a β-hydroxy aldehyde or ketone as an intermediate. ### Step 3: Formation of the Enolate Ion In the presence of the dilute base (e.g., NaOH), acetaldehyde can lose a proton (H⁺) to form an enolate ion. The enolate ion is a nucleophile that can attack the carbonyl carbon of benzaldehyde. **Hint:** Look for the formation of the enolate ion, as it is a key step in aldol reactions. ### Step 4: Nucleophilic Attack The enolate ion formed from acetaldehyde attacks the carbonyl carbon of benzaldehyde. This results in the formation of a β-hydroxy aldehyde. The reaction can be summarized as follows: \[ \text{C}_6\text{H}_5\text{CHO} + \text{CH}_3\text{CHO} \rightarrow \text{C}_6\text{H}_5\text{CH(OH)CH}_2\text{CHO} \] **Hint:** Keep track of the functional groups formed during the reaction. ### Step 5: Dehydration The β-hydroxy aldehyde can undergo dehydration (loss of water) when heated, leading to the formation of an α,β-unsaturated aldehyde. The dehydration step can be represented as: \[ \text{C}_6\text{H}_5\text{CH(OH)CH}_2\text{CHO} \xrightarrow{\text{heat}} \text{C}_6\text{H}_5\text{CH=CHCHO} + \text{H}_2\text{O} \] **Hint:** Dehydration is a common step in aldol condensation reactions, resulting in the formation of double bonds. ### Step 6: Final Product The final product of the reaction is cinnamaldehyde (C₆H₅CH=CHCHO), which is an α,β-unsaturated aldehyde. **Hint:** Identify the final product by checking the structure and confirming it matches the expected outcome of the aldol condensation. ### Conclusion The product formed when benzaldehyde (C₆H₅CHO) and acetaldehyde (CH₃CHO) react in the presence of a dilute base is cinnamaldehyde (C₆H₅CH=CHCHO).

To solve the problem of what product is formed when benzaldehyde (C₆H₅CHO) and acetaldehyde (CH₃CHO) react in the presence of a dilute base, we can follow these steps: ### Step 1: Identify the Reactants The reactants are benzaldehyde (C₆H₅CHO) and acetaldehyde (CH₃CHO). Benzaldehyde is an aromatic aldehyde, while acetaldehyde is an aliphatic aldehyde. **Hint:** Remember that the structure of the aldehydes is crucial for understanding the reaction mechanism. ### Step 2: Understand the Reaction Type ...
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