Home
Class 12
CHEMISTRY
The general order of reactivity of carbo...

The general order of reactivity of carbonyl compounds for nucleophilic addition reactions is -

A

`H_2C=O gt RCHO gt ArCHO gt R_2C=O gt Ar_2C=O`

B

`ArCHO gt Ar_2C=O gt RCHO gt R_2C=O gt H_2C=O`

C

`Ar_2C=O gt R_2C=O gt ArCHO gt RCHO gt H_2C=O`

D

`H_2C=O gt R_2C=O gt Ar_2C=O gt RCHO gt ArCHO`

Text Solution

Verified by Experts

The correct Answer is:
A

The size of the alkyl group, causes hindrance to attacking group. As the number and size of the alkyl groups increase the hindrance to the attack of nucleophile also increases.
Thus the reactivity follows the order
`H_2C = O gt RCHO gt ArCHO gt R_2C = O gt Ar_2C = O`.
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise ASSERTION AND REASON|10 Videos
  • ALDEHYDES AND KETONES

    ERRORLESS|Exercise NCERT BASED QUESTIONS(MISCELLANEOUS CARBONYL)|12 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    ERRORLESS|Exercise Assertion & Reason|20 Videos
  • BIOMOLECULES

    ERRORLESS|Exercise ASSERTION & REASON |16 Videos

Similar Questions

Explore conceptually related problems

The order of reactivity of carbonyl compounds for nucleophilic addition is

The reactivity of carbonyl compounds towards nucleophilic addition reaction gets affected by

Observe the following compounds , The correct reactivity order of above compounds towards nucleophilic addition reaction is :

Carbonyl compounds undergo nucleophilic addition because of :

ERRORLESS-ALDEHYDES AND KETONES-PAST YEARS QUESTIONS
  1. A strong base can abstract an alpha-hydrogen from

    Text Solution

    |

  2. The correct statement regarding a carbonyl compound with a hydrogen at...

    Text Solution

    |

  3. The general order of reactivity of carbonyl compounds for nucleophilic...

    Text Solution

    |

  4. Ketones (R(1)COR(2)):R(1)=R(2)=alkyl group, can be obtained in one ste...

    Text Solution

    |

  5. Consider the following reaction The product ‘A’ is

    Text Solution

    |

  6. Predict the product 'B' in the sequence of reaction HC -= CH overset (...

    Text Solution

    |

  7. A single compound of the structure is obtainable from ozonolysis of w...

    Text Solution

    |

  8. The major product of the following reaction is CH3-underset(CH3)unders...

    Text Solution

    |

  9. , Product A is

    Text Solution

    |

  10. A and B in the following reactions are

    Text Solution

    |

  11. Which of the following is incorrect

    Text Solution

    |

  12. Which of the following compounds will undergo self aldol condensation ...

    Text Solution

    |

  13. Consider the reaction RCHO + NH(2)NH(2) rarr R - CH = N NH(2) What...

    Text Solution

    |

  14. Which of the following does not give brick red ppt. with Fehling solut...

    Text Solution

    |

  15. A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin w...

    Text Solution

    |

  16. Acetaldehyde reacts with

    Text Solution

    |

  17. Reaction of carbonyl compound with one of the following reagents invol...

    Text Solution

    |

  18. The product formed in aldol condensation is

    Text Solution

    |

  19. An organic compound 'X' having molecular formula C(5)H(10)O yield phen...

    Text Solution

    |

  20. On hydrolysis of a "compound", two compounds, are obtained. One of whi...

    Text Solution

    |