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Acetaldehyde reacts with...

Acetaldehyde reacts with

A

Electrophiles only

B

Nucleophiles only

C

Free radicals only

D

Both electrophiles and nucleophiles

Text Solution

Verified by Experts

The correct Answer is:
B

Because carbonyl groups are strongly polarized : partially positive at the carbon end, partially negative at the oxygen end, carbon end is able to attract nucleophiles.
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Acetaldehyde react with HCN :

STATEMENT -I : Acetaldehyde react with nitromethane in presence of dil . NaOH to give 1- nitro -2 propanol STATEMENT -2 : The hydrogen atom of acetaldehyde s more acidic then nitromethene.

Assertion (A): The reaction of 1 mol each of (MeCH==O) with glycerol (overset(1)underset(OH)underset(|)CH_(2)-overset(2)underset(OH)underset(|)CH-overset(3)underset(OH)underset(|)CH_(2)) gives six separable isomers. Reason (R ): Acetaldehydes react with 1-and 2-OH group of glycerol to form five-membered cyclic acetal. In the ring closure, two chiral centres are formed and thus we have pairs of enantiomers: cis and trans. When acetaldehydes react with 1-and 3-OH groups, a six membered cyclic acetal is formed giving two disatereomeric products (cis and trans). These diastereomers are achiral.

When acetaldehyde is reacted with very dilute sodium hydroxide, ____________ is obtained.

Acetone shows similarity with acetaldehyde in reacting to-

Acetaldehyde is :

ERRORLESS-ALDEHYDES AND KETONES-PAST YEARS QUESTIONS
  1. Which of the following does not give brick red ppt. with Fehling solut...

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  2. A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin w...

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  3. Acetaldehyde reacts with

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  4. Reaction of carbonyl compound with one of the following reagents invol...

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  5. The product formed in aldol condensation is

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  6. An organic compound 'X' having molecular formula C(5)H(10)O yield phen...

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  7. On hydrolysis of a "compound", two compounds, are obtained. One of whi...

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  8. Which of the following reagents would distinguish ciscyclopenta -1,2-d...

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  9. Of the following which is the product formed when cyclohexanone under...

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  10. Consider the reaction Identify A, X, Y and Z

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  11. Compound A,C(8)H(10)O, is found to react with NaOI (produced by reacti...

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  12. Acetaldehyde cannot exhibit

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  13. Trichloroacetaldehyde, C Cl(3)CHO reacts with chlorobenzene in presenc...

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  14. Paraldehyde is used as a

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  15. C2H5OH and RCOOC2H5 can be separated from CH3CHO using

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  16. Acetone is treated with excess of ethanol in the presence of hydrochlo...

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  17. Phenylmethanol can be prepared by reducing the benzaldehyde with :

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  18. CH3CHO and C6H5CH2CHO can be distinguished chemically by

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  19. Reaction by which benzaldehyde cannot be prepared is :

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  20. Predict the product in the given reaction

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