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Which one of the following nitro compoun...

Which one of the following nitro compounds when react with nitrous acid followed by treatment with alkali produces blue colour?

A

2-methyl-2-nitropropane

B

2-methyl-1-nitropropane

C

2-nitropropane

D

Nitrobenzene

Text Solution

Verified by Experts

The correct Answer is:
C

Nitro group attached to secondary carbon atom will give pseudo nitrol with `HNO_(2)` which on further treatment with alkali gives blue colour
`underset(underset(CH_(3))(|))overset(overset(CH_(3))(|))(HC)- NO_(2) overset(HONO)rarr H_(3)C- underset(underset(NO)(|))overset(overset(CH_(3))(|))(C)- NO_(2) overset(NaOH)rarr` Blue colour
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ERRORLESS-ORGANIC COMPOUNDS CONTAINING NITROGEN-NCERT Based Questions (Properties of Nitrogen Containing Compounds)
  1. Reduction of nitroalkanes in neutral medium (e.g. Zn/NH(4)Cl) forms ma...

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  2. Which one of the following nitro compounds when react with nitrous aci...

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  3. R- NO(2) overset(HNO(2))rarr X overset(NaOH)rarr Blue colour in above ...

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  4. CH(3)Br+KCN(Alco.)to X underset(Na+C(2)H(5)OH)overset("Reduction")to Y...

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  5. The alkyl cynides when ydrolysed to the corresponding acid, the gas ev...

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  6. In the presence of acid, the hydrolysis of methyl cyanides gives

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  7. Reduction of methyl isocyanide gives

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  8. Which one of the following statements about CH(3)CN is not true?

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  9. Given the following sequence of reaction CH(3)CH(2)I overset(NaCN)(r...

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  10. An isocyanide on hydrolysis gives

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  11. Which of the following is not the property of ethanenitrile (CH3CN) ?

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  12. Alkyl cyanides undergo Stephen redyction to produce

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  13. Hydrolysis of phenyl isocyanide forms :

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  14. Complete the following reaction

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  15. The product P in the reaction

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  16. The weakest base among the following is

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  17. When primary amines are treated with HCl, the product obtained is

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  18. Determine the end prodcut of the following reactions C(2)H(5)NH(2) ...

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  19. Primary and secondary amines are distinguished by:

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  20. The decreasing order of basic characters of the three amines and ammon...

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