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R- NO(2) overset(HNO(2))rarr X overset(N...

`R- NO_(2) overset(HNO_(2))rarr X overset(NaOH)rarr` Blue colour in above reaction R is

A

`CH_(3)-`

B

`CH_(3)CH_(2)-`

C

`CH_(3)CH_(2)CH_(2)-`

D

`CH_(3)- underset(underset(CH_(3))(|))(C)H-`

Text Solution

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The correct Answer is:
To solve the given reaction sequence and identify the alkyl group R that leads to the formation of a blue color, we can follow these steps: ### Step 1: Identify the structure of the nitro compound The starting compound is represented as R-NO₂. We need to determine the structure of R that will lead to the formation of a blue color in the final product. ### Step 2: Consider possible alkyl groups We are looking for an alkyl group R that is likely to produce a blue color when reacted with HNO₂ and then with NaOH. Common alkyl groups to consider are methyl (CH₃), ethyl (C₂H₅), isopropyl (C₃H₇), and others. ### Step 3: Analyze the reaction with HNO₂ When R-NO₂ is treated with HNO₂, it undergoes a reaction that typically involves the formation of a diazonium compound. The structure of R will influence the stability of the resulting compound. ### Step 4: Determine the specific alkyl group After analyzing the possible alkyl groups, we find that isopropyl (C₃H₇) is a suitable candidate. The reaction would yield isopropyl nitrite (C₃H₇-NO) upon reaction with HNO₂. ### Step 5: Reaction with NaOH When isopropyl nitrite is treated with NaOH, it forms a pseudo-nitro compound. This compound is known to produce a blue color when dissolved in an alkaline solution. ### Step 6: Conclusion Based on the analysis, the alkyl group R that leads to the formation of a blue color in the reaction is isopropyl (C₃H₇). ### Final Answer: R is isopropyl (C₃H₇). ---

To solve the given reaction sequence and identify the alkyl group R that leads to the formation of a blue color, we can follow these steps: ### Step 1: Identify the structure of the nitro compound The starting compound is represented as R-NO₂. We need to determine the structure of R that will lead to the formation of a blue color in the final product. ### Step 2: Consider possible alkyl groups We are looking for an alkyl group R that is likely to produce a blue color when reacted with HNO₂ and then with NaOH. Common alkyl groups to consider are methyl (CH₃), ethyl (C₂H₅), isopropyl (C₃H₇), and others. ...
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ERRORLESS-ORGANIC COMPOUNDS CONTAINING NITROGEN-NCERT Based Questions (Properties of Nitrogen Containing Compounds)
  1. Reduction of nitroalkanes in neutral medium (e.g. Zn/NH(4)Cl) forms ma...

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  2. Which one of the following nitro compounds when react with nitrous aci...

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  3. R- NO(2) overset(HNO(2))rarr X overset(NaOH)rarr Blue colour in above ...

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  4. CH(3)Br+KCN(Alco.)to X underset(Na+C(2)H(5)OH)overset("Reduction")to Y...

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  5. The alkyl cynides when ydrolysed to the corresponding acid, the gas ev...

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  6. In the presence of acid, the hydrolysis of methyl cyanides gives

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  7. Reduction of methyl isocyanide gives

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  8. Which one of the following statements about CH(3)CN is not true?

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  9. Given the following sequence of reaction CH(3)CH(2)I overset(NaCN)(r...

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  10. An isocyanide on hydrolysis gives

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  11. Which of the following is not the property of ethanenitrile (CH3CN) ?

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  12. Alkyl cyanides undergo Stephen redyction to produce

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  13. Hydrolysis of phenyl isocyanide forms :

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  14. Complete the following reaction

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  15. The product P in the reaction

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  16. The weakest base among the following is

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  17. When primary amines are treated with HCl, the product obtained is

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  18. Determine the end prodcut of the following reactions C(2)H(5)NH(2) ...

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  19. Primary and secondary amines are distinguished by:

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  20. The decreasing order of basic characters of the three amines and ammon...

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