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The reaction between primary amine, chlo...

The reaction between primary amine, chloroform and few drops of alcoholic KOH is known as:

A

Cannizzaro reaction

B

Carbylamine reaction

C

Wurtz's reaction

D

Reimer-Tiemann reaction

Text Solution

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The correct Answer is:
B
`CH_(3)NH_(2) + CHCl_(3) + 3KOH rarr underset("Isocyanide")(R overset(oplus)(N)) -= overset(Θ)(C) + 3KCl + 3H_(2)O`
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The compound obtained by heating the mixture of primary amine, chloroform and alcoholic potassium hydroxide is:

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Reaction of ethylamine with chloroform in alcoholic KOH gives

ERRORLESS-ORGANIC COMPOUNDS CONTAINING NITROGEN-NCERT Based Questions (Properties of Nitrogen Containing Compounds)
  1. Carbylamine test is used in the detection of

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  2. Primary, secondary and tertiary amines can be distinguished by

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  3. The reaction between primary amine, chloroform and few drops of alcoho...

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  4. The end product of the reaction, Ethyl amine overset(HNO(2))rarr(A)o...

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  5. Which of the following is the weakest Bronsted base?

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  6. Benzylamine may be alkylated as shown in the following equation C(...

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  7. The order of basicity of amines in gaseous state is-

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  8. The amine 'A' when treated with nitrous acid gives yellow oily substan...

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  9. Ethyl amine undergoes oxidation in the presence of KMnO4 to form

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  10. Rection of primary amines with aldehyde yields

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  11. In the chemical reaction CH(3)CH(2)NH(2) + CHCI(3) + 3KOH rarr (A) +...

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  12. The compound which on rection with aqueous nirous acid at low temperat...

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  13. The correct order of basicities of PhNH(2)(A), and Ph(2)NH(B) and cycl...

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  14. Correct order of increasing basicity is

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  15. Which one of the following is the strongest base in aqueous solution?

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  16. The following compound can be classified as N-N dimethyl propanamine, ...

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  17. Arrange the following in increasing order of their basic strength: (...

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  18. The amine which can react with C(6)H(5)-SO(2)-Cl to form a product ins...

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  19. n-butylamine(I), diethylamine (II) and N,N-dimethylethylamine (III) ha...

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  20. Complete the following reaction: RNH(2)+H(2)SO(4)to

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