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CH(3)CH(2)Br underset(Delta)overset(Aq.K...

`CH_(3)CH_(2)Br underset(Delta)overset(Aq.KOH)to A underset(Delta)overset(KMnO_(4)//H^(+))to B underset(Delta)overset(NH_(3))to C underset("Alkali")overset(Br_(2))toD`, D is

A

`CH_(3)Br`

B

`CH_(3)CONH_(2)`

C

`CH_(3)NH_(2)`

D

`CHBr_(3)`

Text Solution

Verified by Experts

The correct Answer is:
C
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Consider the following sequence of reactions: CH_3CH_2Br undersetDeltaoverset"aq. KOH"to A undersetDeltaoverset(KMnO_4//H^+)to B undersetDeltaoverset(NH_3)to C underset"Alkali"overset(Br_2)to D , D is

CH_(3)-CH=CH_(2)underset(773 K)overset(Br_(2))to[A]underset("Heat")overset(KOH(alc.))to[B]

Give the structures of A, B and C in the following reactions (i) CH_(3)CH_(2)I overset(NaCN)(to) A underset("hydrolysis Partial")overset(OH^(-))(to) B overset(NaOH+Br_(2))to C (ii) C_(6)H_(5)N_(2)Cl overset(CuCN)to A overset(H_(2)O // H^(+))(to) B underset(Delta)overset(NH_(3))(to) C (iii) CH_(3)CH_(2)Br overset(KCN)to A overset(LiAlH_(4))to B underset(0^(@)C)overset(HNO_(2))to C (iv) C_(6)H_(5)NO_(2) overset(Fe//HCl)to A underset(273 K)overset(NaNO_(2)+HCl)to B underset(Delta)overset(H_(2)O // H^(+))to C (v) CH_(3)COOH underset(Delta)overset(NH_(3))to A overset(NaOBr)to B overset(NaNO_(2)//HCl)to C (vi) C_(6)H_(5)NO_(2) overset(Fe//HCl)to A underset(273 K)overset(HNO_(2))to B overset(C_(6)H_(5)OH)to C

R-COOHunderset(Delta)overset(ND_(3))to(A)underset(Delta)overset(Br_(2),KOH)to(B)overset(NaNO_(2)+HCl)to(C)

Give the structures of the products A, B and C in the following reactions: (i) CH_(3)CH_(2)Br overset(KCN)(to) A overset(LiAlH_(4))(to) B underset(0^(@)C)overset(HNO_(2))(to) C (ii) CH_(3)COOH underset(Delta)overset(NH_(3))(to) A overset(NaOH + Br_(2))(to) B overset(CHCl_(3) + alc KOH)(to) C

Give the structures of A, B and C in the following reactions: (i) CH_(3)Br overset(KCN)(to) A overset(LiAlH_(4))(to) B underset(273 K)overset(HNO_(2))(to) C (ii) CH_(3)COOH underset(Delta)overset(NH_(3))(to) A overset(Br_(2)+KOH)(to) B overset(CHCl_(3)+NaOH)(to) C (iii) CH_(3)CN overset(H_(2)O"/"OH^(-))(to) A underset(Delta)overset(NH_(3))(to)B overset(Br_(2)+KOH)(to) C

CH_(3)COOHoverset(NaOH)to[A]underset(CaO)overset(NaOH)to[B]underset(hv)overset(Br_(2))to[C]

CH_(3)-CH_(2)-underset(Br)underset(|)(CH)-CH_(3)underset(Delta)overset("alc.KOH")rarrX (Major)

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