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Assertion : In CH(3)NCO, the angles C - ...

Assertion : In `CH_(3)NCO`, the angles `C - N - C` and `N - C - O` are not identical
Reason :N- atom has a pair of electrons which is involved to `p pi - d pi ` delocalisation whereas `C-`atom does not have lone pair of electrons.

A

If both assertion and reason are true and the reason is the correct explanation of the assertion.

B

If both assertion and reason are true but reason is not the correct explanation of the assertion.

C

If assertion is true but reason is false.

D

If the assertion and reason both are false.

Text Solution

Verified by Experts

The correct Answer is:
A

`BF_(3)` is an electron deficient molecule and `Me_(3)N` is an electron rich molecule. The electron pair on nitrogen atom in `Ph_(3)N` is delocalized in benzene rings and not available to boron in `BF_(3)`
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