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Glucose and fructose form...

Glucose and fructose form

A

Same osazone

B

Same acid on oxidation

C

Same alcohol when reduced

D

Different osazone

Text Solution

Verified by Experts

The correct Answer is:
A

Osazones formation test involves the reaction of a reducing sugar (free carbonyl group) with excess of phenylhydrazine when kept at boiling temperature. All reducing sugars form osazones.
Glucose – D and Fructose – D, differ in their structures in `C_1` and `C_2` . When they are reacted with phenyl hydrazine these two C – atoms get involved in the reaction and thus structural difference disappears with the formation of same osazone as the structures from `C_3` to `C_6` being same in both the structures.
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Explore conceptually related problems

(a). Glucose and fructose form the same osazone, what does it prove? (b). Why more than 3mol "of"PhNHNH_(2) do not react with glucose and fructose and how does PhNHNH_(2), which is a powerful reducting agent, act as an oxidising agent in this case?

Glucose and fructose from identical osazones because :

Glucose and fructose are

Glucose and fructose are:

Assertion : Reaction of boh glucose and fructose with excess of phenylhydrazine gives the same osazone. Reason : Both glucose and fructose are monosaccharides in nature.

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