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A vessel contains 14 g (7 moles ) of hyd...

A vessel contains `14` g (`7` moles ) of hydrogen and `96` g (`3`moles) of oxygen at `STP`. Chemical reaction is induced by passing electric spark in the vessel till one of the gases is consumed. The temperature is brought back to it's starting value `273 K` .The pressure in the vessel is-

A

0.1 atm

B

0.2 atm

C

0.3 atm

D

0.4 atm

Text Solution

Verified by Experts

The correct Answer is:
A

If electric spark is passed, hydrogen reacts with oxygen to form water `(H_2O)`.
Each gram of hydrogen reacts with eight grams of oxygen.
The gas left in the vessel will be 2 gm of hydrogen i.e. no. of moles ` = 2/2 = 1`
(`:. 96/9 = 12 gm` consumed hydrogen)
Initial no. of moles = 7 + 3 = 10 moles.
`:. p_2/p_1 = n_2/n_1 rArr P_2 = 1/10 = 0.1 atm`.
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