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During the qualitative analysis of salt ...

During the qualitative analysis of salt with cation `y^(2+)` , addition of a reagent (X) to alkaline solution of the salt gives a bright red precipitate. The reagent (X) and the cation `(y^(2+))` present Question: respectively are:

A

Dimethylglyoxime and `Ni^(2+)`

B

Dimethylglyoxime and `Co^(2+)`

C

Nessler's reagent and `Hg^(2+)`

D

Nessler's reagent and `Ni^(2+)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the cation \( y^{2+} \) and the reagent \( X \) that produces a bright red precipitate when added to an alkaline solution of the salt. ### Step-by-Step Solution: 1. **Understanding the Cation**: We know that the cation \( y^{2+} \) is a divalent cation. We need to consider common divalent cations that can form colored complexes. 2. **Identifying the Reagent**: The reagent \( X \) must be able to react with the cation \( y^{2+} \) in an alkaline medium to produce a bright red precipitate. 3. **Common Reagents and Their Reactions**: - Nickel (Ni) ions can form a complex with Dimethylglyoxime (DMG) in alkaline conditions, resulting in a bright red precipitate of nickel dimethylglyoxime complex. - Other cations like cobalt (Co) and copper (Cu) do not produce a bright red precipitate with DMG. 4. **Conclusion**: Based on the known reactions, the cation \( y^{2+} \) is likely Nickel \( (Ni^{2+}) \) and the reagent \( X \) is Dimethylglyoxime (DMG). When nickel ions react with DMG in an alkaline solution, they form a bright red precipitate. ### Final Answer: - Cation \( y^{2+} \): Nickel \( (Ni^{2+}) \) - Reagent \( X \): Dimethylglyoxime (DMG)
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