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Compound A contains 8.7% Hydrogen, 74% C...

Compound A contains 8.7% Hydrogen, 74% Carbon and 17.3% Nitrogen. The molecular formula of the compound is,
Given : Atomic masses of C, H and N are 12,1 and 14 amu respectively.
The molar mass of the compound A is 162 g `mol^(-1)`.

A

`C_4H_6N_2`

B

`C_2H_3N`

C

`C_5H_7N`

D

`C_(10)H_(14)N_2`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the molecular formula of compound A, we will follow these steps: ### Step 1: Convert the percentage composition to grams Assuming we have 100 g of the compound, we can directly use the percentage values as grams: - Hydrogen (H): 8.7 g - Carbon (C): 74 g - Nitrogen (N): 17.3 g ### Step 2: Calculate the number of moles of each element Using the atomic masses: - Hydrogen (H) = 1 g/mol - Carbon (C) = 12 g/mol - Nitrogen (N) = 14 g/mol Now, we calculate the moles: - Moles of H = mass / molar mass = 8.7 g / 1 g/mol = 8.7 mol - Moles of C = mass / molar mass = 74 g / 12 g/mol = 6.17 mol - Moles of N = mass / molar mass = 17.3 g / 14 g/mol = 1.23 mol ### Step 3: Find the simplest mole ratio To find the simplest ratio, we divide each mole value by the smallest number of moles calculated: - Smallest number of moles = 1.23 (for N) Now, we calculate the ratios: - Ratio of H = 8.7 mol / 1.23 mol ≈ 7.07 (approximately 7) - Ratio of C = 6.17 mol / 1.23 mol ≈ 5.02 (approximately 5) - Ratio of N = 1.23 mol / 1.23 mol = 1 Thus, the empirical formula is approximately C5H7N. ### Step 4: Calculate the empirical formula mass Now we calculate the molar mass of the empirical formula (C5H7N): - Molar mass = (5 × 12) + (7 × 1) + (1 × 14) = 60 + 7 + 14 = 81 g/mol ### Step 5: Determine the molecular formula Given that the molar mass of the compound A is 162 g/mol, we can find the ratio of the molecular formula mass to the empirical formula mass: - Ratio = Molar mass of compound / Empirical formula mass = 162 g/mol / 81 g/mol = 2 ### Step 6: Multiply the empirical formula by this ratio To find the molecular formula, we multiply the subscripts in the empirical formula (C5H7N) by 2: - Molecular formula = C(5×2)H(7×2)N(1×2) = C10H14N2 ### Final Answer The molecular formula of compound A is C10H14N2. ---

To determine the molecular formula of compound A, we will follow these steps: ### Step 1: Convert the percentage composition to grams Assuming we have 100 g of the compound, we can directly use the percentage values as grams: - Hydrogen (H): 8.7 g - Carbon (C): 74 g - Nitrogen (N): 17.3 g ...
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