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The exhibition of highest co-ordination ...

The exhibition of highest co-ordination number depends on the availability of vacant orbitals in the central atom. Which of the following elements is not likely to act as central atom in `MF_(6)^(3-)` ?

A

B

B

Al

C

Ga

D

In

Text Solution

Verified by Experts

The correct Answer is:
A

The lowest atomic number among the given is boron. Boron has atomic number 5 and do not have vacant dorbital. The element M in the complex ion `MF_(6)^(3-)` has a coordination number of six. Boron can show maximum coordination number of 4. Thus, B can not form complex of the type `MF_(6)^(3-)`
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