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Soldiers of Napolean army while at alps ...

Soldiers of Napolean army while at alps during freezing winter suffered a serious problem as regards to the tin buttons of their uniforms. White metallic tin buttons got converted to grey powder. This transformation is related to

A

A change in the partial pressure of oxygen in the air

B

A change in the crystalline structure of tin

C

An interaction with nitrogen of the air at very low to temperatures

D

An interaction with water vapour contained in the humid air

Text Solution

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The correct Answer is:
B

Grey tin is very brittle and easily crumbles down to a powder in very cold climates.
`underset("(Cubic)")("Grey tin") hArr underset("(Tetragonal)")("White tin")`
The change of white tin to grey tin is accompanied by increase in volume. This is called tin disease or tin plague.
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The soldiers of Napoleon army while at Alps during freezing winter suffered a serious problem with regard to the tin buttons of their uniform. White metallic tin buttons get converted to grey poweder. This transformation is relate to