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Assuming oxygen molecule to be spherical...

Assuming oxygen molecule to be spherical in shape, calculate the volume of a single molecule of oxygen if its radius is 150 pm. Also calculate the percentage of empty space in one mole of the gas at STP.

Text Solution

Verified by Experts

The correct Answer is:
`99.26`

As Oxygen molecule is spherical , therefore , volume of one molecule = `4/3 pi r^(3)`
`= 4/3 xx 22/7 (150 xx 10^(-10)cm)^(3) = 1.41 xx 10^(-23) cm^(3)`
To calculate the empty space in 1 mole of `O_(2)` molecules , let us first calculate the volume occupied by 1 mole of molecules , i.e., `6.022 xx 10^(23)` molecules . This will be
`= ( 6.022 xx 10^(23)) xx (1.41 xx 10^(-23) cm^(3)) = 8.49 cm^(3)`
But volume occupied by 1 mole of molecules at S.T.P
` = 22400 cm^(3)`
` :. ` empty space = `22400 - 8.49 cm^(3) = 22391.51 cm^(3)`
` :. ` % age of empty space = `(22391.51)/22400 xx 100 = 99.6 % `
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