Home
Class 11
CHEMISTRY
Assuming CO(2) to be van der Waals gas, ...

Assuming `CO_(2)` to be van der Waals gas, calculate its Boyle temperature. Given `a=3.59" L"^(2)" atm " mol^(-2)` and `b=0.0427" L "mol^(-1)`.

Text Solution

Verified by Experts

The correct Answer is:
1024

Boyle temperature in terms of van der Waals constants is : `T_(B) = a/(Rb)` . Hence ,
`T_(B) = (3.59L^(2)"atm mol"^(-2))/((0.0821 " L atm L"^(-1)mol^(-1))(0.0427" L mol"^(-1)))=1024 K `.
Promotional Banner

Similar Questions

Explore conceptually related problems

Calculate the pressure exerted by 110 g of carbon dioxide in a vessel of 2 L capacity at 37^(@)C . Given that the van der Waal’s constants are a = 3.59 L^(2) " atm "mol^(-2) and b = 0.0427 L mol^(-1) . Compare the value with the calculated value if the gas were considered as ideal.

Calculate the critical constants of a gas whose van der Waals constants are : a=0.751" L"^(2)" atm "mol^(-2) and b=0.0226" L mol"^(-1) .

One mole of CO_(2) occpuies 1.5 L at 25^(@)C . Calculate the pressure exerted by the gas using (i) ideal gas equation van der Waals gas equation with a=3.6 L^(2)" bar mol"^(-2) and b="0.04 L mol"^(-1)

Calculate the pressure excerted by 5 mol of CO_(2) in 1 L vessel at 47^(@)C using van der Waals equation. Also report the pressure of gas if it behaves ideally in nature. (a=3.592 atm L^(2) mol^(-2), b=0.0427 L mol^(-1))

Pressure exerted by 1 mole of methane in a 0.25 litre container at 300K using Vander Waal’s equation : (Given : a = 2.253 "atm" l^(2) "mol"^(-2) and b = 0.0428 l "mol"^(-1) ) is

Calculate the temperature of 2 moles of sulphur dioxide gas contained in a 5 L vessel at 10 bar pressure. Given that for SO_(2) gas, van der Waals constants are : a=6.7 bar L^(2) mol^(-2) and b=0.0564 L mol^(-1) .

A vessel of 25 L capacity contains 10 mol of steam under 50 bar pressure. Calculate the temperature of steam using van der Waals equation if for water : a="5.46 bar L"^(2)"mol"^(-2) and b="0.031 L mol"^(-1) .

Calculate the pressure exerted by 22g of CO_(2) in 0.5 dm^(3) at 300 K using ( a ) the ideal gas law and ( b ) the van der Waals equation. Given a=300.0 kPa dm^(6) mol^(-2) and b=40.0 cm^(3) mol^(-1) .