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Correct order of bond angles for the fol...

Correct order of bond angles for the following is

A

`NH_3 gt PCl_3 gt BCl_3`

B

`BCl_3 gt NH_3 gt PCl_3`

C

`BCl_3 gt PCl_3 gt NH_3`

D

`PCl_3 gt BCl_3 gt NH_3`

Text Solution

Verified by Experts

The correct Answer is:
B

`BCl_3` is trigonal in shape where bond angle is `120^@`. In `NH_3 and PCl_3` (both are having tetrahedral geometry) though the central atom has equal no. of lone pairs and bond pairs, the valence shell of P is relatively bigger and bond angle is lower.
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