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Passing H(2)S gas into a mixture of Mn^(...

Passing `H_(2)S` gas into a mixture of `Mn^(2+), Ni^(2+), Cu^(2+)` and `Hg^(2+)` ions in an acidified aqueous solution precipitates

A

CuS and HgS

B

MnS and CuS

C

MnS and NiS

D

NiS and HgS

Text Solution

Verified by Experts

The correct Answer is:
A

In presence of acidic medium, ionisation of `H_(2)S` is suppressed so less number of `S^(2-)` ions are produced. So only those sulphides are precipitated which have low solubility product `(K_(sp))`value , For example CuS and HgS.
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