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pH of a buffer solution decreases by 0.0...

pH of a buffer solution decreases by 0.02 units when 0.12g of acetic acid is added to 250mL of a buffer solution of acetic acid and potassium acetate at `27^(@)`C. The buffer capacity of the solution is

A

`0.1`

B

10

C

1

D

`0.4`

Text Solution

Verified by Experts

The correct Answer is:
D

No. of moles of acetic acid = `0.12//60 = 2 xx 10^(-3)`
Buffer Capacity
`= ("No . of moles of acid added per litre of solution")/("Change in pH units")`
`phi = (2xx10^(-3)//250 xx10^(-3)" moles/L")/(0.02)`
`phi = 0.4`
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