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The pH of ammonium phosphate solution, i...

The pH of ammonium phosphate solution, if `pK_(a)` of phosphoric acid and `pK_(b)` of ammonium hydroxide are 5.23 and 4.75 respectively, is _______.

Text Solution

Verified by Experts

The correct Answer is:
7

Since `(NH_(4))_(3)PO_(4)` is salt of weak acid `(H_(3)PO_(4))` and weak base `(NH_(4)OH)`.
`pH=7+(1)/(2)(pK_(a)-pK_(b))`
`=7+(1)/(2)(5.23-4.75)=7.24~~7`
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