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Cr(2)O(7)^(2-)+I^(-)toI(2)+Cr^(3+) E(c...

`Cr_(2)O_(7)^(2-)+I^(-)toI_(2)+Cr^(3+)`
`E_(cell)^(@)=0.79V,E_(Cr_(2)O_(7)^(2-))^(@)=1.33V,E_(I_(2))^(o)` is

A

`-0.10 V`

B

`+0.18 V`

C

`-0.54 V`

D

0.54 V

Text Solution

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The correct Answer is:
D

Properties of ionic solid
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Given E_(Cl_(2)//Cl^(-))^(@)=1.36V,E_(Cr^(3+)//Cr)^(@)=-0.74V E_("Cr_(2)O_(7)^(2-)//Cr^(3+))^(@)=1.33V,E_(MnO_(4)^(-)//Mn^(2+))^(@)=1.51V Among the following, the strongest reducing agent is