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The magnitude of crystal field stabilisa...

The magnitude of crystal field stabilisation energy (CFSE of `Delta_(1)`) in tetrahedral complexes is considerably less than that in the octahderal field. Because

A

There are only four ligands instead of six so the ligand field is only 2/3 the size hence the `Delta_t` is 2/3

B

The direction of the orbitals does not coincide with the direction of the ligands. This reduces the crystal field stabilization energy `(Delta)` by further 2/3

C

Both points (a) and (b) are correct

D

Both points (a) and (b) are wrong

Text Solution

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The correct Answer is:
C

Properties of ionic solid
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