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The enthalpy of dissolution of BaCl(2)(s...

The enthalpy of dissolution of `BaCl_(2)(s) and BaCl_(2).2H_(2)O` are -20.6 and 8.8 KJ `mol^(-1)` respectively . Calculate enthalpy of hydration forgiven reaction:
`BaCl_(2)(s)+2H_(2)OtoBaCl_(2).2H_(2)O(s)`

A

29.4 kJ

B

– 11.8 kJ

C

– 20.6 kJ

D

– 29.4 kJ

Text Solution

Verified by Experts

The correct Answer is:
D

(i) `BaCl_2(s) to BaCl_2(aq) , Delta H =-20.6 kJ//mol`
(ii) `BaCl_2. 2H_2O (s) to BaCl_2(aq) + 2H_2O(l) , Delta H, = 8.8 kJ//mol`
Subtracting eq.(ii) from eq.(i)
`BaCl_2(s) + 2H_2O(l) to BaCl_2 . 2H_2O(s)`
`DeltaH = (-20.6 - 8.8) kJ//mol`
`DeltaH = - 29.4kJ//mol`.
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