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The decreasing order of nucleophilicity ...

The decreasing order of nucleophilicity among the nucleophiles
is

A

(i), (ii), (iii), (iv)

B

(iv), (iii), (ii), (i)

C

(ii), (iii), (i), (iv)

D

(iii), (ii), (i), (iv)

Text Solution

Verified by Experts

The correct Answer is:
C

The acidic strength follows the order:
`CH_3 - Ph - SO_3H gt CH_3 COOH gt HCN gt CH_3 OH`
Hence the basic character of conjugate base will follow the order:
`CH_3 O^(-) gt CN^(-) gt CH_3COO^(-) gt CH_3 - Ph - SO_3H`
Generally nucleophilicity follows the basic character, so the decreasing order of nucleophilicity:
(ii) > (iii)>(i)>(iv)
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