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n-pentane and iospentane can be distingu...

`n-`pentane and iospentane can be distinguished by

A

`Br_(2)`

B

`O_(3)`

C

Conc. `H_(2)SO_(4)`

D

`KMnO_(4)`

Text Solution

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The correct Answer is:
D

On oxidation, with `KMnO_4` they give different alcohols
`underset("n-pentane")(CH_(3)CH_(2)CH_(2)CH_(2)CH_(3)) overset(KMnO_4)underset([O]) rarr underset(1^@ "alcohol")(CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)OH) CH_(3)-underset(CH_3)underset(|)(CH)-CH_3 overset(KMnO_4)underset([O])rarrCH_(3)underset(3^@ "alcohol")(CH_2-overset(OH)overset(|)underset(CH_3)underset(|)C-CH_(3)`
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