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Copper is extracted from copper pyr...

Copper is extracted from copper pyrites by heating in a bessemer converter. The method is based on the principle that

A

Copper has less affinity for oxygen than sulphur at high temperature

B

Copper has more affinity for oxygen than sulphur at high temperature

C

Sulphur has less affinity for oxygen at high temperature

D

Iron has less affinity for oxygen than sulphur at high temperature

Text Solution

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The correct Answer is:
B

The method is based on the principle that copper has more affinity for oxygen than sulphur at high temperature.
Reaction of Bassemerisation
`FeS + O_(2) rarr FeO + SO_(2) , FeO + SiO_(2) rarr underset("Slag")(FeSiO_3 darr)`
`CuS + O_(2) rarr Cu_(2)O + SO_(2)`
`Cu_(2)O + underset("Pyrites")underset("copper")(Cu_2S) overset("Auto")underset("oxidation")rarrunderset("copper")underset("Blister")(Cu darr) + SO_2`
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