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Knowing that the chemistry of lanthanoid...

Knowing that the chemistry of lanthanoids (Ln) is dominated by its `+3` oxidation state, which of the following statement is incorrect?

A

Because of the large size of the Ln (III) ions the bonding in its compounds is predominantly ionic in character

B

The ionic sizes of Ln (III) decrease in general with increasing atomic number

C

Ln(III) compounds are generally colourless

D

Ln (III) hydroxides are mainly basic in character

Text Solution

Verified by Experts

The correct Answer is:
C

Most of the trivalent lanthanoid compounds except that of `La^(3+) and Lu^(3+)` are coloured both in the solid state and in the aqueous solution. The colour of these ions can be attributed due to the presence of f-electrons.
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