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Among the following substituted silanes,...

Among the following substituted silanes, the one which will give rise to cross linked silicone polymer on hydrolysis is?

A

`RSiCl_(3)`

B

`R_(2)SiCl_(2)`

C

`R_(3)SiCl`

D

`R_(4)Si`

Text Solution

Verified by Experts

The correct Answer is:
A

`R_(2)SiCl_(2)` can form linear polymer due to two replaceable Cl atom. `R_(3)SiCl` can terminate the reaction because it has only one replaceable Cl atom upon hydrolysis Cl atom is replaced by -OH group) and thus it cannot polymerise.
`R SiCl_(3)` has 3 replaceable Cl atoms which upon hydrolysis can form cross linked silicone polymer.
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