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Metallic tin in the presence of HCl is o...

Metallic tin in the presence of HCl is oxidized by `K_(2)Cr_(2)O_(7)` to stannic chloride, `SnCl_(4)` . What volume of deci-normal dichromate solution would be reduced by 1 g of tin.

A

168.49 mL

B

175.49 mL

C

170.50 mL

D

162.38 mL

Text Solution

Verified by Experts

The correct Answer is:
A

`overset((+2))(SnCl_(2)) to overset((+4))(SnCl_(4))`
Equivalent wt. 2
No. of g. equivalents `= (1g)/(119//2g) = (2)/(119)`
` 0.1 xx V = 2 //119`
`V = 168.07` mL
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