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Amount of oxalic acid present in a solut...

Amount of oxalic acid present in a solution can be determined by its titration with `KMnO_(4)` solution in the presence of `H_(2)SO_(4)`. The titration gives unsatisfactory result when carried out in the presence of HCl because HCl:

A

Furnishes `H^(+)` ions in addition to those from oxalic acid

B

Reduces permanganate to `Mn^(2+)`

C

Oxidises oxalic acid to carbon dioxide and water

D

Get oxidised by oxalic acid to chlorine

Text Solution

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The correct Answer is:
B

HCl is a strong reducing agent. It reduces `MnO_(4)^(-)` (oxidation no. = 7) to `Mn^(2+)` (oxidation no. = 2) and hence the result of the titration becomes unsatisfactory
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