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Which one of the following does not form...

Which one of the following does not form sodium bisulphite addition product with sodium bisulphite solution

A

`CH_3OH`

B

`C_6H_5COCH_3`

C

`C_6H_5CHO`

D

`CH_3CHO`

Text Solution

Verified by Experts

The correct Answer is:
B
Crystalline solid derivatives are formed when aldehydes or ketones are shaken with saturated aqueous solution of sodium bisulphite, but sodium bisulphite is a bigger nucleophile so, all ketones do not give this test. Only aliphatic methyl ketones form addition product with sodium bisulphite.
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