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Which of following species does not exer...

Which of following species does not exert a resonance effect

A

`C_(6)H_(5)OH`

B

`C_(6)H_(5)Cl`

C

`C_(6)H_(5)NH_(2)`

D

`C_(6)H_(5) overset(+)(N)H_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D
`C_(6)H_(5) overset(..)(N)H_(2) + H^(+) rarr underset("Anilinium ion")(C_(6) H_(5) overset(+)(N)H_(3))`
Anilinium ion formed by aniline on accepting a proton is less resonance stabilised than aniline. Due to absence of lone pair in conjugation of double bond of benzene it does not exert a resonance effect.
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