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In the following compounds, the decreasi...

In the following compounds, the decreasing order of basic strength will be

A

`(C_2H_5)_2NH gt C_2 H_5NH_2 gt NH_3`

B

`(C_2H_5)_2 NH gt NH_3 gt C_2H_5NH_2`

C

`NH_3 gt C_2H_5NH_2 gt (C_2H_5)_2 NH`

D

`C_2H_5NH_2 gt NH_3 gt (C_2H_5)_2 NH`

Text Solution

Verified by Experts

The correct Answer is:
A
`(C_2H_5)_2 overset(* *)NH gt overset(* *)N(C_2H_5)_3 gt C_2H_5NH_2 gt NH_3`
This is experimental basic strength order. Which is the combined result of solvation and electronic effect.
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